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Introduction The Model (VSEPR) Examples
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The VSEPR Model

The electrons around the atoms in a molecule repel each other.  They move to be as far apart as possible while still maintaining the bonding within the molecule.  The procedure for using the model is as follows:

  1. Determine the correct Lewis structure for the molecule.  If it is a diatomic (has only two atoms) it is linear and falls into the AX category.  If it has 3 or more atoms continue with step 2.
  2. Count the number of electron groups around the central atom.  A group of electrons is a bond, a nonbonding electron pair, or occasionally an unpaired nonbonding electron.  Each triple or double bond counts as only one group for the purposes of this model.
  3. Based on this number of groups around the central atom the molecule falls into one of six basic categories. Within each category there are a number of different names for the shapes depending upon the number of atoms and nonbonding groups around the central atom.
Below is a Summary Table of the categories and names for the various sub-shapes.
VSEPR Summary Table
Number of Groups around central atom Shape when all groups are bonded atoms
Electron geometry and molecular geometry are the same
(click links to see examples you can manipulate)
Sub-Shapes (molecular geometry)
A = central atom, X = atom attached to central atom, E = nonbonding electron group on central atom
(click links to see examples you can manipulate)
Diatomic
(any number of groups)
Linear Diatomic
diatomic molecule
AX wedge diagram

Linear (AX)

2
Linear Triatomic
linear triatomic
AX2 wedge diagram

Linear (AX2)

3
Trigonal Planar
trigonal planar molecule
AX2E wedge diagram

Bent (AX2E)

4 Tetrahedral
tetrahedral molecule
AX4 wedge diagram

Tetrahedral (AX4)

AX2E2 wedge diagram

Bent (AX2E2)

5
Trigonal Bipyramidal
trigonal bipyramidal molecule
AX4E wedge diagram

See-Saw (AX4E)

AX3E2 wedge diagram

T-Shaped (AX3E2)

AX2E3 wedge diagram

Linear (AX2E3)

6 Octahedral
Octahedral molecule
Last Update: September 13, 2026
Expires: --
J. Gutow